This is an ionic species consisting of a long, linear, nonpolar tail with a cationic or anionic head and a counter ion. Sulphonation technology in the detergent industry by w. Soap manufacturing technology, second edition, is the most authoritative and uptodate book on soap technology available today. Sulphonation technology in the detergent industry springerlink. Treatment of soap and detergent industry wastes constantine yapijakis the cooper union, new york, new york, u. Applications of sulfonation sulfonation is effective in reducing evaporative emissions of plastics. Anionic surfactants are the key component in a detergent formulation. It identifies and examines a range of important current topics and issues that will potentially impact the industry in the years to come. Applications of sulfonation sulfo technologies, llc. About 2,500,000 tons of sulphonated anionic surfactants are produced annually in the u. Chemically sulfation refers to the conversion of a molecule into a sulfate.
Technical evaluation report sodium dodecylbenzene sulfonate sdbs handling. Production cost report lase11a,lase21a xxx linear alkylbenzene sulfonate linear alkylbenzene sulfonate las linear alkylbenzene sulphonic acid linear alkylbenzene sulfonate a. But the production technology of detergents have been changed involving. Download all the sulphonation technology in the detergent industry icons you need.
Chemithon sulfonation technologies take best in class at concours d sulfonation. The altmetric attention score is a quantitative measure of the attention that a research article has received online. Labsa industry has low technology barrier and is labor intensive industry. By sulfonation, alkylbenzene sulfonate is produced. Sulfonationtechnology, patents, process, turnkey, equipments. Sulfonationsulfation processing technology for anionic surfactant manufacture chapter pdf available march 2012 with 7,055 reads how we measure reads. Profitable business ideas for starting detergent business. Sulphonation technology in the detergent industry 1991, springer netherlands free ebook download as pdf file.
Pdf sulfonationsulfation processing technology for. Airso3 sulfonation plants ranging in size from 5 kghr to over 20,000 kghr turbo tube dryer for producing concentrated detergent actives 96% active powder production systems 1,4dioxane reduction system drs for ether sulfates lubricating oil sulfonation methyl ester sulfonation alphaolefin sulfonation. Furthermore, technological advancements are also likely to fuel the growth. Principles of our sulfonation process sulfo technologies, llc. For purposes of studying the industry and developing effluent limitations guidelines for existing sources and standards of performance, the soap and detergent industry has been divided into nineteen discrete subcate. For raw materials to be used, quantities to be used and ingredients usage rankings, you should look into this formulation. This book is about sulphonation technology in its technical entirety, aiming at superiority in final product quality.
This book is about sulphonation technology in its technical entirety, aiming at superiority in final product quality, raw material utilisation, sustained plant reliability and safety, minimisation of liquid effluent and gaseous emissions. A typical detergent composition is shown in table 1. The mechanism of the sulfonation process journal of the. In todays detergents, builders constitute about 625wt.
Sulphonation technology in the detergent industry semantic scholar. The reader is recommended to refer those documents for specific details of the toxicity data studies. The total annual world production of sulphonated anionic surfactants is estimated at about 4,000,000 tons. Sulfonation with sulfuric acid is a special case of oleum sulfonation. A brief description of the sulphonation processes used for the manufacture of. Preparation and production of high grade sulfonic acid. Pdf sulfonation of polyethylene improves functionality. Sulphonation technology in the detergent industry icons. Also the sulfonation process described are only for so3.
Soap and detergent manufacture nz institute of chemistry. For the production, there is need usable and tried a formulation, raw materials and mixing tank. It includes a characterization of the industry, an overview of the different process types, a description of emissions, and a description of the technology used to control emissions resulting from soap and detergent production. Soaps and detergents are used frequently in our daily life. Economic census data are available, this industry had 799 establishments2. Sulphonation technology in the detergent industry 1991. The largest soap market is bar soap used for personal bathing.
Aryl sulfonic acids are used as detergents, dye, and drugs stoichiometry and mechanism. Because the sulfonation reaction stops when the acid concentration in the reaction mixture drops to less than approximately 90%, sulfonation of detergent feedstocks with sulfuric acid is not normally practiced. Surface modification wettability, reduction in the angle of contact with water, hydrophilizing, etching, ion exchanging. Plants manufacturer of soap, edible oil, fatty acids, detergent powder. Aryl sulfonic acids are used as detergents, dye, and drugs. For purposes of studying the industry and developing effluent limitations guidelines for existing sources and standards of performance, the soap and detergent industry has been divided into. Its also effective in achieving the following properties in various plastics. Aromatic sulfonation is an organic reaction in which a hydrogen atom on an arene is replaced by a sulfonic acid functional group in an electrophilic aromatic substitution.
Currently, there are many producing companies in the world labsa industry. Processes used for the manufacture of active detergents. The main market players are ho tung, cepsa, sasol, kapachim, stepan, new india detergents, isu chemical and nanjing gige. Detergent alkylates world markets, 20062016 is a comprehensive study which details the production, capacity, trade and supplydemand balance by region for both linear and branched alkylbenzenes. Learn more about these metrics article views are the countercompliant sum of full text article downloads since november 2008 both pdf and html across all institutions and individuals. The indian detergent industry is about three decades old. Application of sulphonates as anionic surfactants in household products. Today, our customers use chemithon airso3 sulfonation systems to produce surfactants used in a wide variety of consumer and industrial products, as well as oil additives.
Related icons include technology icons, industry icons, device icons, computer icons, internet icons, factory icons, network icons, communication icons, mobile icons. Pdf sulfonationsulfation processing technology for anionic. We use them to wash our hands and clean our clothes without ever really paying. Raw materials for linear alkyl benzene production are benzene and kerosene that comes out of fractionation distillation towers along temperature range 190250 c. Sulfonation process of palm methyl ester as anionic surfactant. The complete technology book on detergents 2nd revised edition. Linear alkylbenzene sulfonate production cost reports 201920. Laundry detergent market size, share, analysis industry. Linear alkylbenzene sulfonate production cost reports.
The soaps, detergent and acid slurry product industry are vivacious, varied, creative and tricky, and have the prospective to provide a gratifying career. Detergents are commonly available as powders or concentrated solutions. Secondary alkane sulfonate sas cas 68037490 hera project. An interesting and unique feature of detergent industry in india is the existence of non power operated units which do not use any electrical power for the production of detergent powder. Environmental safety of the use of major surfactant classes in. Choose between 98540 sulphonation technology in the detergent industry icons in both vector svg and png format. Today sulfuric acid sulfonation is principally used for. Sulfonation of polyethylene improves functionality for fabricating technical textiles article pdf available january 2014 with 1,250 reads how we measure reads.
General industry information the soap industry includes companies primarily engaged in making soap, synthetic organic detergents, inorganic alkaline detergents, and crude and refined glycerin from vegetable and animal fats. The largest chemithon division emerged from the companys invention of the continuous oleum sulfonation process in the mid1950s. Sulfonationsulfation processing technology for anionic. What is sulfation or sulfonation biosynthesis, inc. Major factors affecting the outlook are examined including raw material requirements, surfactant consumption trends, novel technological. Microsoft powerpoint advances in sulfonation technologies author. The rising penetration of washing machines in the developing economies is likely to be key driver for demand over the forecast period. Boston wikipedia citation please see wikipedias template documentation for further citation fields that may be required. This is not comprehesive enough but useful especially for practical knowledge of so3 sulfonation. So3 sulfonation plantdetergent powderwashing powderlaundry. Sulfonation of plastics is a process of treating the surface region with sulfur trioxide gas and various neutralization agents to modify the molecular structure of the surface region of the plastic. T1 sulphonation technology in the detergent industry.
More specifically, it is the addition of a sulfate group as an ester group to a target molecule such as a hydroxyl group connected to a hydrophobic moiety. Pdf sulfonation of polyethylene improves functionality for. A brief description of the sulphonation processes used for. Editor and contributing author luis spitz leads a worldrenowned team in providing comprehensive information on all components of soap manufacturing including formulation, performance evaluation, cleansing systems, and more. The complete technology book on detergents 2nd revised. It will be of value to engineers and chemists who are, or will be, involved in the practical daily. Advances in sulfonation and sulfation technologies luigi perani for. Sulphonation technology in the detergent industry w.
Airs03 sulfation and sulfonation 88 s03 solvent and vacuum sulfonation 88 sulfamic acid sulfation 88 neutralization of sulfuric acid esters and sulfonic acids 89 spray dried detergents 89 liquid detergents 90 dry detergent blending 90 drum dried detergents 90 detergent bars and cakes 90 industrial cleaners 90. Principles of our sulfonation process sulfo technologies. Xi detergents asoap2 the chemistry of soap and detergent function all soaps and detergents contain a surfactant1 as their active ingredient. But the production technology of detergents have been changed involving high technique in. Over 10 million scientific documents at your fingertips. Apr, 2010 sulphonation technology in the detergent industry by w. Powder detergent production is not very complicated. Production of linear alkyl benzene sulphonic acid labsa.
The term detergent by itself refers specifically to laundry detergent or dish detergent, as opposed to hand soap or other types of cleaning agents. These metrics are regularly updated to reflect usage leading up to the last few days. Sulfonation process used for the manufacturing of anionic surfactants sulfonation reactions can be carried out in different configurations, either liquidliquid contact, or gasliquid contact reactors, and a di versity of sulfonating reagents can be applied for the sulfonation process, such as. Manufacturing and packaging process of soaps, detergents. Using our unique sulfonation technology sulfonation using anhydrous sulfate gas, we are able to handle a wide variety of products. The global laundry detergent market size was valued at usd 3. Sas is one of the major anionic surfactants used in the market of. Aise is the voice of the detergents and cleaning products industry in europe. Petroleum industry in general, the products which dictate refinery design are relatively few in number, and the basic refinery processes are based on the largequantity products such as gasoline, diesel, jet fuel, and home heating oils.
Sulfonation alters the chemical structure of a polymeric substrate by introducing sulfonic groups on its surface region. In chemistry, a sulfate refers to a salt or ester of sulfuric acid. So3 sulfonation plantdetergent powderwashing powder. Low sulphonation, energy efficient mechanical pulping.
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